TRIS(N-BUTYL)PHOSPHINE, TRIS(TERT-BUTYL)PHOSPHINE AND TRIS(TRIMETHYL-SILYL)PHOSPHINE

Authors
BRUCKMANN J KRUGER C
Citation
J. Bruckmann et C. Kruger, TRIS(N-BUTYL)PHOSPHINE, TRIS(TERT-BUTYL)PHOSPHINE AND TRIS(TRIMETHYL-SILYL)PHOSPHINE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1152-1155
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
6
Pages
1152 - 1155
Database
ISI
SICI code
0108-2701(1995)51:<1152:TTAT>2.0.ZU;2-G
Abstract
Single crystals of the title compounds, C12H27P (1), C12H27P (2), and C9H27PSi3 (3), were grown in capillaries at low temperature using zone -melting techniques [Brodalla, Mootz, Boese & Osswald (1985). J. Appl. Cryst. 18, 316-319]. The molecular and crystal structures of all thre e compounds were determined at 102 K. Compound (1) has a pseudo-mirror plane and C-P-C angles between 100.5 (1) and 102.7 (1)degrees. Compou nd (2) has a pseudosymmetric threefold rotation axis and C-P-C angles of 107.1 (1), 107.4 (1) and 107.8 (1)degrees. Isomorphous compound (3) has Si-P-Si angles between 105.8 (1) and 106.5 (1)degrees.