2-CYANO-2-METHYLSPARTEINE

Authors
WOLSKA I BOROWIAK T
Citation
I. Wolska et T. Borowiak, 2-CYANO-2-METHYLSPARTEINE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1158-1160
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
6
Pages
1158 - 1160
Database
ISI
SICI code
0108-2701(1995)51:<1158:2>2.0.ZU;2-B
Abstract
In the title compound, [7S-(7 alpha,7a alpha,14 alpha,14a yrido[1,2-a: 1',2'-e][1,5]diazocine-4-carbonitrile, C17H27N3, the two quinolizidine moieties have been found to have trans A/B and trans C/D configuratio ns. The piperidine rings A, B, C and D assume chair, chair, boat and c hair conformations, respectively. The methyl substituent has been show n to adopt an equatorial orientation, with the cyano substituent in an axial position.