THE EFFECT OF SUBSTITUENTS ON THE CRYSTAL-STRUCTURE OF BETA-AMINO ALCOHOLS - 3,4-DIMETHOXYBENZYL)(METHYL)AMINO]-2-PHENYLETHANOL

Authors
URTIAGA MK ARRIORTUA MI BADIA D DOMINGUEZ E GONZALEZCAMENO AM OCHANDO L REVENTOS M DEBAERDEMAEKER T
Citation
Mk. Urtiaga et al., THE EFFECT OF SUBSTITUENTS ON THE CRYSTAL-STRUCTURE OF BETA-AMINO ALCOHOLS - 3,4-DIMETHOXYBENZYL)(METHYL)AMINO]-2-PHENYLETHANOL, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1175-1177
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
6
Pages
1175 - 1177
Database
ISI
SICI code
0108-2701(1995)51:<1175:TEOSOT>2.0.ZU;2-4
Abstract
The crystal structure of ,4-dimethoxybenzyl)(methyl)amino]-2-phenyleth anol, C18H23NO3, (I), has been determined. The influence of the type a nd size of the groups bonded to the N atom in the crystal structure of (I) was studied and compared with the influence of such groups on the crystal structure of ybenzyl)(p-toluenesulfonyl)amino]-2-phenylethano l, (II). The N atom of compound (I) shows sp(3) character and is syncl inal to the OH group, while the N atom of compound (II) shows sp(2) ch aracter and is antiperiplanar to the OH group.