KINETIC MODELING OF THE OXIDATIVE COUPLING OF METHANE OVER LANTHANUM OXIDE IN CONNECTION WITH MECHANISTIC STUDIES

Authors
LACOMBE S DURJANOVA Z MLECZKO L MIRODATOS C
Citation
S. Lacombe et al., KINETIC MODELING OF THE OXIDATIVE COUPLING OF METHANE OVER LANTHANUM OXIDE IN CONNECTION WITH MECHANISTIC STUDIES, Chemical engineering & technology, 18(3), 1995, pp. 216-223
Citations number
10
Categorie Soggetti
Engineering, Chemical
Journal title
Chemical engineering & technology → ACNP
ISSN journal
09307516
Volume
18
Issue
3
Year of publication
1995
Pages
216 - 223
Database
ISI
SICI code
0930-7516(1995)18:3<216:KMOTOC>2.0.ZU;2-#
Abstract
A kinetic model of the oxidative coupling of methane (OCM) over lantha num oxide is developed on the basis of mechanistic conclusions obtaine d elsewhere. A reaction scheme is proposed, and the kinetic parameters corresponding to the different kinetic equations are optimized. Exper imental and calculated reaction rates are compared with the aim of tes ting the proposed scheme and validating the basic mechanistic assumpti ons.