9-9'-BIFLUORENYLIDENE (BFD) COMPLEXES OF RUTHENIUM [((ETA(5)-C(5)ME(5))RU)N(BFD)](X) (X=O, N=1, X=1(- EPR AND SPECTROELECTROCHEMICAL STUDIES - X-RAY STRUCTURE OF [((ETA(5)-C(5)ME(5))RU)(BFD)](OSO2CF3)(), N=2) )

Authors
OTERO M ROMAN E SAMUEL E WITTKE O
Citation
M. Otero et al., 9-9'-BIFLUORENYLIDENE (BFD) COMPLEXES OF RUTHENIUM [((ETA(5)-C(5)ME(5))RU)N(BFD)](X) (X=O, N=1, X=1(- EPR AND SPECTROELECTROCHEMICAL STUDIES - X-RAY STRUCTURE OF [((ETA(5)-C(5)ME(5))RU)(BFD)](OSO2CF3)(), N=2) ), Inorganica Chimica Acta, 234(1-2), 1995, pp. 1-4
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
234
Issue
1-2
Year of publication
1995
Pages
1 - 4
Database
ISI
SICI code
0020-1693(1995)234:1-2<1:9(COR[>2.0.ZU;2-W
Abstract
[(eta(5)-C(5)Me(5))Ru](+) coordinates to the six-membered aromatic rin gs of the bifluorenylidene (BFD) chromophore to afford mononuclear [(e ta(5)-C(5)Me(5))Ru(BFD)](+) and dinuclear [[(eta(5)-C(5)Me(5))Ru](2)(B FD)](2+) compounds which could be isolated as trifluoromethane sulfona te salts, 1(OTf) and 2(OTf)(2), respectively. The X-ray structure of 1 was determined and both compounds were studied by spectroelectrochemi cal methods and their reduced species by EPR.