SYNTHESIS OF TRIOSMIUM ALKYLIDYNE CLUSTERS INCORPORATING PENDANT PYRIDYL LIGANDS - CRYSTAL-STRUCTURES OF U-H)(2)(CO)(9)(MU(3)-C(4,4'-BIPY))]-CENTER-DOT-H2O AND [OS-3(MU-H)(2)(CO)(9)(MU(3)-C(2,4'-BIPY))] (4,4'-BIPY=4,4'-BIPYRIDINE, 2,4'-BIPY=2,4'-BIPYRIDINE)

Authors
WONG WY WONG WT HU SZ
Citation
Wy. Wong et al., SYNTHESIS OF TRIOSMIUM ALKYLIDYNE CLUSTERS INCORPORATING PENDANT PYRIDYL LIGANDS - CRYSTAL-STRUCTURES OF U-H)(2)(CO)(9)(MU(3)-C(4,4'-BIPY))]-CENTER-DOT-H2O AND [OS-3(MU-H)(2)(CO)(9)(MU(3)-C(2,4'-BIPY))] (4,4'-BIPY=4,4'-BIPYRIDINE, 2,4'-BIPY=2,4'-BIPYRIDINE), Inorganica Chimica Acta, 234(1-2), 1995, pp. 5-8
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
234
Issue
1-2
Year of publication
1995
Pages
5 - 8
Database
ISI
SICI code
0020-1693(1995)234:1-2<5:SOTACI>2.0.ZU;2-V
Abstract
Reaction of [Os-3(mu-H)(3)(CO)(9)(mu(3)-CCl)] with 1,8-diazabicyclo[5. 4.0]undec-7-ene (DBU) in the presence of an excess of 4,4'-bipyridine (4,4'-bipy) or 2,4'-bipyridine (2,4'-bipy) yields [Os-3(mu-H)(2)(CO)(9 )(mu(3)-C(4,4'-bipy))] (1) and [Os-3(mu-H)(2)(CO)(9)(mu(3)-C(2,4'bipy) )] (2), respectively, in good yields. Both complexes, which contain ex ternally directed pendant pyridyl groups capable of ligation to other metal centres, have been fully characterised by spectroscopic and X-ra y diffraction methods. Chemical reactivities of 1 with H+, AuPPh(3)(+) and [Os-3(mu-H)(3)(CO)(9)(mu(3)-CCl)] are also described.