Powder processing techniques for MoSi2 composites are described. The e
ffect of Nb morphology on the fracture resistance of the composites wa
s studied. Discontinuous random Nb particles or fibers deflected crack
s that propagated through the MoSi2 matrix. However, this did not resu
lt in any improvements in toughness (as measured from the area under f
lexural stress-displacement curves). Aligned Nb fibers oriented perpen
dicular to the direction of matrix crack propagation directly particip
ated in the fracture of the composite; these fibers toughened MoSi2. H
owever, there was an effect of the diameter on the fracture behavior o
f the aligned fibers. The effect of fiber diameter on fiber-matrix sep
aration could be explained through the load carrying capacity of the f
ibers and the ability of the fiber-matrix interface to separate.