The behaviour of both chlorine dioxide and chlorine, either as an indi
vidual or as combined disinfectants were studied on effluents from act
ivated sludge. The results of the disinfection efficiency, residual di
sinfectants, and their by-products, obtained by treating the same effl
uents at the same day with identical dosing Sequence of chlorine dioxi
de and chlorine, alone and in a combined dosing, were compared after p
eriods of the same contact. In most cases, it seems that each disinfec
tant maintains its individual capabilities when used in a combined man
ner. The combination produced a relatively stable high residual of bot
h disinfectants. The important finding is the fact that the combinatio
ns of chlorine dioxide and chlorine decreased the concentration of the
undesirable chlorite ion and increased the concentration of the newly
formed chlorine dioxide. A greater advantage is obtained by using chl
orine dioxide prior to chlorine. Therefore, combined disinfection in t
his sequence is recommended.