THE HIGH-RESOLUTION NU(7) PERPENDICULAR BAND OF JET-COOLED SI2F6

Authors
TOSA V URBAN RD TAKAMI M TAKEUCHI K
Citation
V. Tosa et al., THE HIGH-RESOLUTION NU(7) PERPENDICULAR BAND OF JET-COOLED SI2F6, Journal of molecular spectroscopy, 172(1), 1995, pp. 254-264
Citations number
11
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular spectroscopy → ACNP
ISSN journal
00222852
Volume
172
Issue
1
Year of publication
1995
Pages
254 - 264
Database
ISI
SICI code
0022-2852(1995)172:1<254:THNPBO>2.0.ZU;2-4
Abstract
The vibration-rotation spectrum of the perpendicular band nu(7) of (Si 2F6)-Si-28,28 has been studied in a supersonic free jet with 0.001 cm( -1) resolution. The spectrum covering the K Delta K = -17 to 8 subband s shows a local perturbation for K Delta K > 2. The whole spectrum has been successfully analyzed by assuming a Fermi interaction from a ver y close combination state. Also. the Q branch of the nu(7) band of (Si 2F6)-Si-28,29 has been identified. (C) 1995 Academic Press, Inc.