URANYL-SULFATE GRAPHITE-INTERCALATION COMPOUNDS .1. THEIR SYNTHESIS AND STABILITY

Authors
MOISSETTE A DUBESSY J FUZELLIER H BURNEAU A LELAURAIN M
Citation
A. Moissette et al., URANYL-SULFATE GRAPHITE-INTERCALATION COMPOUNDS .1. THEIR SYNTHESIS AND STABILITY, Carbon, 33(6), 1995, pp. 809-815
Citations number
18
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Carbon → ACNP
ISSN journal
00086223
Volume
33
Issue
6
Year of publication
1995
Pages
809 - 815
Database
ISI
SICI code
0008-6223(1995)33:6<809:UGC.TS>2.0.ZU;2-L
Abstract
Stability of new graphite-uranyl-sulfate intercalation compounds was s tudied experimentally as a function of temperature and concentration. The action of uranyl-sulfuric acid aqueous solution leads to the forma tion of two mixed-phase intercalation products: the usual sulfate phas e (d(i) = 798 pm) and a new uranyl-sulfate phase (d(i) = 855 pm). This latter phase is obtained alone after desorption of the sulfate phase, due to the lower thermal stability of the sulfate phase.