ELECTRONIC-STRUCTURE OF LINIO2, LIFEO2 AND LICRO2 - X-RAY PHOTOELECTRON AND X-RAY-EMISSION STUDY

Citation
Vr. Galakhov et al., ELECTRONIC-STRUCTURE OF LINIO2, LIFEO2 AND LICRO2 - X-RAY PHOTOELECTRON AND X-RAY-EMISSION STUDY, Solid state communications, 95(6), 1995, pp. 347-351
Citations number
19
Categorie Soggetti
Physics, Condensed Matter
Journal title
ISSN journal
00381098
Volume
95
Issue
6
Year of publication
1995
Pages
347 - 351
Database
ISI
SICI code
0038-1098(1995)95:6<347:EOLLAL>2.0.ZU;2-F
Abstract
We present X-ray photoelectron (XPS) and soft X-ray emission (XES) spe ctra of LiNiO2, LiFeO2 and LiCrO2. The concentration of holes per oxyg en ion in LiNiO2 is estimated and a classification of the investigated oxides is given. We propose, that LiFeO2 should be placed in the inte rmediate region between a charge-transfer and a Mott-Hubbard insulator and LiCrO2 can most likely be assigned to the Mott-Hubbard insulators .