Objectives and methods: The relationship between dentine bonding and t
he condition of dentine for four dentine bonding systems (All Bond 2,
Clearfil Liner Bond, Scotchbond MP and XR Bond) has been examined. Dif
ferent dentine conditions were evaluated and correlated with adhesion
values. Dentine permeability was calculated using a hydraulic pressure
apparatus working under physiological pulpal pressure (6.9 kPa), whil
e remaining dentine thickness (RDT) was measured using pincer calipers
. Scanning electron microscopic (SEM) examinations were effected to an
alyse dentine morphology. These evaluations were considered as an inde
x of the condition of dentine. Shear bond strength tests were used to
evaluate adhesion. Dentine samples after the bonding systems applicati
on were stored for 24 h under pulpal pressure before bond strength was
tested. Results: Scanning electron microscopy examinations indicated
that the application of bonding system conditioners caused the removal
of smear layer, the demineralization of dentine and the formation of
a layer of collapsed collagen fibrils in the intertubular and peritubu
lar dentine. Primers were able to infiltrate the collagen fibrils. A l
ayer of resin infiltrated/reinforced dentine (the so-called 'hybrid la
yer') was observed for All Bond 2, Clearfil Liner Bond and Schotchbond
MP. Conclusions: Significant correlations were observed only for XR B
ond, which proved very sensitive to RDT and dentine permeability despi
te the presence of smear layer. The other three materials did not show
any correlation with dentine conditions. By contrast they showed the
highest bond values.