The influence of ferrocene, iron benzoate, iron naphthoate and iron ac
etylacetonate on the pyrolysis of Ashland A240 petroleum pitch was inv
estigated. The additives are catalyst precursors for iron-catalysed py
rolysis with the following aims: (1) acceleration of the pyrolysis rea
ctions; (2) production of pitches with improved coke yield-glass trans
ition temperature relationship; and (3) conversion of organically to i
norganically bound sulfur, which is less critical for coke puffing.