THE ENANTIOMERIC EXCESS PHOSPHORIC-ACIDS USED FOR RESOLUTION

Authors
HULST R KRUIZINGA W WYNBERG H FERINGA BL KELLOGG RM
Citation
R. Hulst et al., THE ENANTIOMERIC EXCESS PHOSPHORIC-ACIDS USED FOR RESOLUTION, Recueil des travaux chimiques des Pays-Bas, 114(4-5), 1995, pp. 220-224
Citations number
27
Categorie Soggetti
Chemistry
Journal title
Recueil des travaux chimiques des Pays-Bas → ACNP
ISSN journal
01650513
Volume
114
Issue
4-5
Year of publication
1995
Pages
220 - 224
Database
ISI
SICI code
0165-0513(1995)114:4-5<220:TEEPUF>2.0.ZU;2-D
Abstract
A method is presented to determine the enantiomeric excess (ee) of pho sphoric acids 1, which are extensively used as resolving agents, by me ans of diastereomeric salt formation with chiral amines. The unexpecte d dynamic behaviour of these systems leads us to postulate a model, wh ich we refer to as non-reciprocal behaviour.