TRANSITION FROM THE DEFORMED STRUCTURE TO THE STATISTICALLY EQUIVALENT IDEAL STRUCTURE AND AN ESTIMATE OF THE BASIC PHYSICAL CHARACTERISTICS OF THE DEFORMED STRUCTURE
Bs. Tosic et al., TRANSITION FROM THE DEFORMED STRUCTURE TO THE STATISTICALLY EQUIVALENT IDEAL STRUCTURE AND AN ESTIMATE OF THE BASIC PHYSICAL CHARACTERISTICS OF THE DEFORMED STRUCTURE, Physica. A, 216(4), 1995, pp. 478-488
A procedure is proposed enabling the substitution of a translationally
non-invariant one-dimensional structure with unequal neighbouring spa
cing by a statistically equivalent ideal structure with equal spacing
between neighbouring molecules. A procedure of statistical averaging o
f the intermolecular spacing is applied to some typical intermolecular
potential in order to estimate its physical plausibility. The main co
nclusion is that non-ideality of the structure makes the transport of
elementary excitations more difficult with respect to the same transpo
rt through the ideal structure.