HYDROXY-ASSISTED CHEMOSELECTIVE AND STEREOSELECTIVE EPOXIDATION CATALYZED BY A TITANIUM SILICATE MOLECULAR-SIEVE (TS-1) H2O2 SYSTEM/

Authors
KUMAR R PAIS GCG PANDEY B KUMAR P
Citation
R. Kumar et al., HYDROXY-ASSISTED CHEMOSELECTIVE AND STEREOSELECTIVE EPOXIDATION CATALYZED BY A TITANIUM SILICATE MOLECULAR-SIEVE (TS-1) H2O2 SYSTEM/, Journal of the Chemical Society, Chemical Communications, (13), 1995, pp. 1315-1316
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
13
Year of publication
1995
Pages
1315 - 1316
Database
ISI
SICI code
0022-4936(1995):13<1315:HCASEC>2.0.ZU;2-5
Abstract
The TS-1/H2O2 system efficiently catalyses the hydroxy-assisted chemos elective epoxidation of alpha-hydroxyalkene in geraniol, and the stere oselective epoxidation of cyclopent-2-en-1-ol/cyclohex-2-en-1-ol produ cing the epoxide which is cis to OH with high selectivity (90:10 cis: trans).