SAMARIUM(II) IODIDE PROMOTED RING CONTRACTION OF CARBOHYDRATE-DERIVATIVES - AN EXPEDITIOUS SYNTHESIS OF FUNCTIONALIZED CYCLOPENTANES

Authors
CHENEDE A POTHIER P SOLLOGOUB M FAIRBANKS AJ SINAY P
Citation
A. Chenede et al., SAMARIUM(II) IODIDE PROMOTED RING CONTRACTION OF CARBOHYDRATE-DERIVATIVES - AN EXPEDITIOUS SYNTHESIS OF FUNCTIONALIZED CYCLOPENTANES, Journal of the Chemical Society, Chemical Communications, (13), 1995, pp. 1373-1374
Citations number
27
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
13
Year of publication
1995
Pages
1373 - 1374
Database
ISI
SICI code
0022-4936(1995):13<1373:SIPRCO>2.0.ZU;2-P
Abstract
Aldehydo methyl pyranosides undergo ring contraction induced by treatm ent with samarium(ii) iodide, in the presence of HMPA and tert-butyl a lcohol, to give highly functionalised cyclopentanes.