COMPLETE RETENTION OF CONFIGURATION IN THE NUCLEOPHILIC-SUBSTITUTION OF 1-PHENYLBENZO[B]THIOPHENIUM SALTS BY ALKOXIDE ANIONS

Authors
KITAMURA T MIYAJI M SODA S TANIGUCHI H
Citation
T. Kitamura et al., COMPLETE RETENTION OF CONFIGURATION IN THE NUCLEOPHILIC-SUBSTITUTION OF 1-PHENYLBENZO[B]THIOPHENIUM SALTS BY ALKOXIDE ANIONS, Journal of the Chemical Society, Chemical Communications, (13), 1995, pp. 1375-1376
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
13
Year of publication
1995
Pages
1375 - 1376
Database
ISI
SICI code
0022-4936(1995):13<1375:CROCIT>2.0.ZU;2-0
Abstract
Reaction of 1,2,3-triarylbenzo[b]thiophenium salts with alkoxide anion s results in:the exclusive formation of (Z) alkoxy-substituted alkenes , indicating that the nucleophilic ring-opening reaction proceeds with complete retention of configuration.