A SHORT SYNTHESIS OF C-GLYCOSYL PYRAZOLES AND PYRROLES

Citation
Jl. Delvalle et al., A SHORT SYNTHESIS OF C-GLYCOSYL PYRAZOLES AND PYRROLES, Journal of heterocyclic chemistry, 32(3), 1995, pp. 899-901
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0022152X
Volume
32
Issue
3
Year of publication
1995
Pages
899 - 901
Database
ISI
SICI code
0022-152X(1995)32:3<899:ASSOCP>2.0.ZU;2-Q
Abstract
The sodium salt of TOSMIC reacted with ,7-penta-O-acetyl-1,2-dideoxy-1 -C-nitro-D-galacto- (1) and -D-manno-hept-1-enitol (2) to give 3-(D-ga lacto- (3) and -manno-penta-O-acetylpentitol-1-yl)-4-nitropyrrole (4), respectively. Compound 1 reacted with diaryl nitrile imines, affordin g 5-penta-O-acetyl-D-galacto-pentitol-1-yl)pyrazoles 5 and 6.