OXIDATION OF 5-HYDROXYMETHYLFURFURAL AND DERIVATIVES TO FURANALDEHYDES WITH 2,2,6,6-TETRAMETHYLPIPERIDINE OXIDE RADICAL - COOXIDANT PAIRS

Citation
L. Cottier et al., OXIDATION OF 5-HYDROXYMETHYLFURFURAL AND DERIVATIVES TO FURANALDEHYDES WITH 2,2,6,6-TETRAMETHYLPIPERIDINE OXIDE RADICAL - COOXIDANT PAIRS, Journal of heterocyclic chemistry, 32(3), 1995, pp. 927-930
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0022152X
Volume
32
Issue
3
Year of publication
1995
Pages
927 - 930
Database
ISI
SICI code
0022-152X(1995)32:3<927:OO5ADT>2.0.ZU;2-O
Abstract
The oxidation of 5-hydroxymethylfurfural (1) or 5-hydroxymethylfurfury Iideneacetophenone (4) with various 4-substituted 2,2,6,6-tetramethylp iperidine radicals (TEMPO) 3a-d and supporting co-oxidants gave corres ponding aldehydes 2 or 5 in fair yields.