PALLADIUM-CATALYZED SYNTHESIS OF DIENYL PHOSPHONATES FROM VINYL TRIFLATES AND DIETHYLVINYL PHOSPHONATE

Authors
BURINI A CACCHI S PACE P PIETRONI BR
Citation
A. Burini et al., PALLADIUM-CATALYZED SYNTHESIS OF DIENYL PHOSPHONATES FROM VINYL TRIFLATES AND DIETHYLVINYL PHOSPHONATE, Synlett, (6), 1995, pp. 677-679
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
6
Year of publication
1995
Pages
677 - 679
Database
ISI
SICI code
0936-5214(1995):6<677:PSODPF>2.0.ZU;2-T
Abstract
The palladium-catalysed vinylic substitution of vinyl triflates with d iethylvinyl phosphonate affords the corresponding conjugate dienyl pho sphonates. Title compounds are isolated in good to high yields in the presence of K2CO3 and n-Bu(4)NCl. Best results, however, are obtained by using the K2CO3/KOAc combination.