A NEW EFFICIENT PREPARATION OF POLYFUNCTIONAL PHOSPHINES USING ZINC ORGANOMETALLICS

Authors
LANGER F KNOCHEL P
Citation
F. Langer et P. Knochel, A NEW EFFICIENT PREPARATION OF POLYFUNCTIONAL PHOSPHINES USING ZINC ORGANOMETALLICS, Tetrahedron letters, 36(26), 1995, pp. 4591-4594
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
26
Year of publication
1995
Pages
4591 - 4594
Database
ISI
SICI code
0040-4039(1995)36:26<4591:ANEPOP>2.0.ZU;2-0
Abstract
The reaction of diorganozincs or organozinc halides with chlorophosphi nes (Ph(n)PCl(3-n)) produces polyfunctional phosphines in high yields. This method has been used to prepare several chiral phosphines in hig h enantiomeric purity.