A new, fast ion-conducting, silver seleno molybdate (SSM), glassy elec
trolyte has been synthesized. Solid-state primary cells of the design
anode/solid electrolyte/cathode have been fabricated with the highest
conducting composition of the SSM glass as the solid electrolyte. The
polarization and discharge characteristics of the cells are studied wi
th different compositions of the cathode material. The effect of addin
g the solid electrolyte and tetraalkylammonium iodide (alkyl=methyl, b
utyl) to the cathode on the cell performance is investigated. The cell
parameters are evaluated and the results are compared with a cell of
the type Ag/AgI/(iodine+graphite) (I+C) that is fabricated using polyc
rystalline AgI as the solid electrolyte.