HYDROGEN-BONDS AND PROTONATION OF CARBONYL-CONTAINING POLYNUCLEAR RHODIUM COMPLEXES

Authors
KRYLOV AN SHUBINA ES MURATOV DV VORONTSOV EV EPSHTEIN LM
Citation
An. Krylov et al., HYDROGEN-BONDS AND PROTONATION OF CARBONYL-CONTAINING POLYNUCLEAR RHODIUM COMPLEXES, Russian chemical bulletin, 44(2), 1995, pp. 378-379
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
2
Year of publication
1995
Pages
378 - 379
Database
ISI
SICI code
1066-5285(1995)44:2<378:HAPOCP>2.0.ZU;2-V
Abstract
According to IR spectroscopy data, the interaction of bi-, tri-, and t etranuclear cyclopentadienylcarbonyl rhodium complexes with rather wea k protic acids (phenols, fluoroalcohols) in low-polarity media results in the formation of hydrogen bonds of the OH...O=C type with bridged carbonyl groups. According to H-1 NMR data, protonation of these compl exes with strong acids (CF3COOH and HBF4) occurs at the the Rh-Rh bond to give the symmetrical [GRAPHICS] bridge.