FORMATION AND STRUCTURE OF A NEW DINUCLEAR RHODIUM COMPLEX [(IPR(3)P)RHCL](2)[P(3)C(3)TBU(3)]

Authors
BINGER P HAAS J BETZ P KRUGER C
Citation
P. Binger et al., FORMATION AND STRUCTURE OF A NEW DINUCLEAR RHODIUM COMPLEX [(IPR(3)P)RHCL](2)[P(3)C(3)TBU(3)], Chemische Berichte, 128(7), 1995, pp. 737-739
Citations number
37
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
128
Issue
7
Year of publication
1995
Pages
737 - 739
Database
ISI
SICI code
0009-2940(1995)128:7<737:FASOAN>2.0.ZU;2-8
Abstract
The new dinuclear rhodium complex 4 was synthesized by reaction of [(i Pr(3)P)(2)RhCl](2) (1) or [(iPr(3)P)(2)(CH2=CH2)RhCl] (2) with 2-tert- butyl-1-phoshaacetylene (3) in 58% yield. An X-ray analysis reveals th at in 4 a 1,3,6-triphosphahexadiene-1,6-diyl chain is bound to each of the two rhodium atoms in an eta(1), eta(3) manner.