HIGH EFFICIENT CATALYTIC-OXIDATION OF STEROIDAL OLEFINS BY METALLOPORPHYRIN-REDUCTANT-MOLECULAR OXYGEN BIOMIMETIC SYSTEMS

Authors
SOLOVIEVA AB BOROVKOV VV LUKASHOVA EA GRINENKO GS
Citation
Ab. Solovieva et al., HIGH EFFICIENT CATALYTIC-OXIDATION OF STEROIDAL OLEFINS BY METALLOPORPHYRIN-REDUCTANT-MOLECULAR OXYGEN BIOMIMETIC SYSTEMS, Chemistry Letters, (6), 1995, pp. 441-442
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1995
Pages
441 - 442
Database
ISI
SICI code
0366-7022(1995):6<441:HECOSO>2.0.ZU;2-I
Abstract
Catalytic oxidation of steroidal olefins by metalloporphyrin-reductant -molecular oxygen systems produces stereoselectively corresponding 5-a lpha-hydroxy derivatives with high yields and the manganese complexes show higher efficiency in comparison with the iron complex due to the difference in metal-porphyrin orbital interactions.