SYNTHESIS AND STRUCTURE OF OCTAHEDRAL NICKEL(IV) COMPLEXES CONTAINING2 CHELATING ACYLPHENOLATO LIGANDS

Authors
KLEIN HF BICKELHAUPT A LEMKE M JUNG T ROHR C
Citation
Hf. Klein et al., SYNTHESIS AND STRUCTURE OF OCTAHEDRAL NICKEL(IV) COMPLEXES CONTAINING2 CHELATING ACYLPHENOLATO LIGANDS, Chemistry Letters, (6), 1995, pp. 467-468
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
6
Year of publication
1995
Pages
467 - 468
Database
ISI
SICI code
0366-7022(1995):6<467:SASOON>2.0.ZU;2-Z
Abstract
2-Acylphenolato complexes Ni(C=O O)(PMe(3))(3) can be oxidized using i odine or diiodoalkanes at ambient conditions to afford ion-spin d(6) c omplexes Ni(C=O O)(2)(PMe(3))(2). The molecular structure of the 5-ter t-butyl-3-methyl derivative contains two axial trimethylphosphines and a cisoidal arrangement of two acylphenolato dianions in equatorial po sitions.