J. Lacaze et G. Lesoult, MODELING THE DEVELOPMENT OF MICROSEGREGATION DURING SOLIDIFICATION OFAN AL-CU-MG-SI ALLOY, ISIJ international, 35(6), 1995, pp. 658-664
In the as-cast state, wrought aluminium alloys present chemical hetero
geneities, the so-called microsegregations, which are due to the parti
tioning of alloying elements between liquid and solid during solidific
ation. While most of the experimental characterizations of solute dist
ribution reported in the literature are dealing with fully solidified
material, this paper presents results related to the build-up of micro
segregation during the solidification of an aluminium alloy. The featu
res of the corresponding cumulative distributions are presented and th
en discussed by comparing them to predictions made with a numerical pr
ogramme which takes into account both the build-up of the main solutes
in the liquid and their diffusion in the solid during the solidificat
ion. From this comparison, it is concluded that the build-up of micros
egregation during the solidification of aluminium alloys could be desc
ribed as a phenomenon which occurs in a spherical elementary volume el
ement the diameter of which equals the dendrite arm spacing, and which
is not greatly affected by the structural coarsening during solidific
ation. The discrepancies between the calculated and measured cumulativ
e distributions at low solid fraction are associated with a bias of th
e experimental distributions due to the physical noise of X-ray emissi
on.