OXIDATION OF CYCLOHEXANE BY TERT-BUTYL HYDROPEROXIDE CATALYZED BY MANGANESE(II) N,N'-ETHYLENE BIS(SALICYLIDENEAMINATO) AND ANALOGOUS COMPLEXES

Authors
GANESHPURE PA TEMBE GL SATISH S
Citation
Pa. Ganeshpure et al., OXIDATION OF CYCLOHEXANE BY TERT-BUTYL HYDROPEROXIDE CATALYZED BY MANGANESE(II) N,N'-ETHYLENE BIS(SALICYLIDENEAMINATO) AND ANALOGOUS COMPLEXES, Journal of molecular catalysis. A, Chemical, 113(3), 1996, pp. 423-425
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
113
Issue
3
Year of publication
1996
Pages
423 - 425
Database
ISI
SICI code
1381-1169(1996)113:3<423:OOCBTH>2.0.ZU;2-6
Abstract
Manganese(II) N,N'-ethylene bis(salicylideneaminato) (1) and analogous manganese(II) complexes 2-5 catalyzed oxyfunctionalization of cyclohe xane by tert-butyl hydroperoxide to give cyclohexanol and cyclohexanon e in high yields at room temperature in acetonitrile solution. A pathw ay involving oxomanganese intermediate is suggested for the reaction.