The generation of hazardous wastes from various sources including chem
ical industries, hospitals, households, etc., is a worldwide problem a
nd is particularly acute in the United States. The petrochemical and r
efinery industries produce about 70% of this waste. Geographically, th
e greatest production of hazardous wastes is known to occur along the
United State Gulf coast. Presently, it is estimated that about 80% of
the total waste remains toxic for years or even centuries. Inappropria
te disposal of these wastes on land creates the risk of contaminating
ground water and vegetation causing adverse health effects. This revie
w addresses the geotechnical aspects of the problems related to the ma
nagement of hazardous waste by the use of polymeric materials as 'barr
iers'. Important findings of research efforts on this topic from 1980
through mid-1994 are discussed. The review gives an awareness to the g
eneral public and addresses points of interest to field engineers and
technologists for the proper handling of wastes by the use of the poly
meric geosynthetics acting as membranes or barriers.