Jh. Shin et Ha. Atwater, GENERALIZED DEFECT ANNIHILATION KINETICS FOR STRUCTURAL RELAXATION INAMORPHOUS-SILICON, Philosophical magazine. B. Physics of condensed matter. Structural, electronic, optical and magnetic properties, 72(1), 1995, pp. 1-11
A general approach to the dynamics of structural relaxation in amorpho
us silicon is developed. A form is chosen for the recombination kineti
cs of defects which removes the ad-hoc assumption made in previous app
roaches, namely that defects recombine only with others of identical a
ctivation energy. The generalized approach is tested quantitatively by
modelling the structural relaxation of amorphous silicon and comparin
g the results with the experimental data. It is found that the general
ized recombination kinetics formalism is necessary in order to describ
e accurately the time-resolved relaxation data.