AN EASY ACCESS TO TETRA-O-ALKYLATED CALIX[4]ARENES OF CONE CONFORMATION

Authors
BITTER I GRUN A AGAI B TOKE L
Citation
I. Bitter et al., AN EASY ACCESS TO TETRA-O-ALKYLATED CALIX[4]ARENES OF CONE CONFORMATION, Tetrahedron, 51(28), 1995, pp. 7835-7840
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
28
Year of publication
1995
Pages
7835 - 7840
Database
ISI
SICI code
0040-4020(1995)51:28<7835:AEATTC>2.0.ZU;2-N
Abstract
Fully O-alkylated calix[4]arenes have been synthesized by the alkylati on of p-tert-buhlcalix[4]arene and its 1.3-dialkylated derivatives in liquid-liquid phase-transfer catalytic process. 1H(4) and 1H(2)R(2) co uld effeciently be deprotonated by aqueous NaOH (50% w/w)-toluene syst em and alkylated with alkyl (aralkyl. allyl) halogens in good yields a ffording calix[4]arene tetraethers of cone conformation.