E. Makino et al., MASKLESS PATTERNING OF GOLD ELECTRICAL CONTACTS BY LASER PLATING IN AFLOWING SOLUTION, International journal of the Japan Society for Precision Engineering, 29(1), 1995, pp. 23-28
Fine gold spots and lines for electrical contacts were deposited from
a flowing plating solution under argon laser irradiation. The effects
of cathode potential, laser power, and solution flow rate were studied
on deposition rate and controllability of deposited pattern size. In
situ observation revealed that vigorous boiling occurs under solution
flow conditions and that laser plating is enhanced by a strong microst
irring due to the ejection of bubbles. Gold electrical contacts of sim
ilar to 1 mu m height are produced in less than 0.5 s for spots, and a
t a laser beam scan speed of more than several hundreds of mu m/s for
lines at a laser power of several watts. The diameter of the spots and
the width of the lines are controlled by laser power and cathode pote
ntial, as well as by laser beam diameter, at less than 100 mu m. Such
laser plated spots and lines have a fine morphology, a high adhesion t
o the substrate, and a low electrical resistivity of 5-15 mu Omega . c
m.