EQUILIBRIUM AND HYDROLYSIS OF ALPHA-AMINO-ACID ESTERS IN MIXED-LIGANDCOMPLEXES WITH N-(ACETAMIDO)-IMINODIACETATECOPPER(II)

Authors
SHOUKRY MM HOSNY WM KHALIL MM
Citation
Mm. Shoukry et al., EQUILIBRIUM AND HYDROLYSIS OF ALPHA-AMINO-ACID ESTERS IN MIXED-LIGANDCOMPLEXES WITH N-(ACETAMIDO)-IMINODIACETATECOPPER(II), Transition metal chemistry, 20(3), 1995, pp. 252-255
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
20
Issue
3
Year of publication
1995
Pages
252 - 255
Database
ISI
SICI code
0340-4285(1995)20:3<252:EAHOAE>2.0.ZU;2-3
Abstract
The formation equilibria of the binary and ternary complexes of Cu-II with N-(acetamido)-iminodiacetic acid (ADA) and amino acids or their e sters were investigated potentiometrically. The chelation mode was asc ertained by conductivity measurements. The kinetics of the base hydrol ysis of amino acid esters in the presence of the copper(II)-ADA comple x were studied. The rate and catalysis constants were estimated.