BINUCLEAR COMPLEXES OF CHROMIUM, MANGANESE AND RHODIUM WITH HYL-N,N',N'-TRIBENZIMIDAZOLYLMETHYLETHYLENEDIAMINE

Authors
YANG LQ YAN SP LIAO DZ JIANG ZH WANG GL SHEN PW
Citation
Lq. Yang et al., BINUCLEAR COMPLEXES OF CHROMIUM, MANGANESE AND RHODIUM WITH HYL-N,N',N'-TRIBENZIMIDAZOLYLMETHYLETHYLENEDIAMINE, Transition metal chemistry, 20(3), 1995, pp. 273-275
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
20
Issue
3
Year of publication
1995
Pages
273 - 275
Database
ISI
SICI code
0340-4285(1995)20:3<273:BCOCMA>2.0.ZU;2-M
Abstract
Three novel binuclear complexes, Cr(2)Cl(6)L . EtOH, Mn(2)OAc(4)L . Et OH, Rh(2)Cl(6)L.2H(2)O, where l-N,N',N'-tribenzimidazolylmethylethylen e-diamine, have been prepared and characterized by elemental analyses, i.r., u.v.-vis. and e.s.r. spectra, and by magnetic susceptibility me asurements. A weak antiferromagnetic spin exchange interaction exists between the metal ions in a binuclear unit for the dimanganese complex . Preliminary bioassays show that the manganese complex possesses anti tumour activity in vitro.