Citation
B. Burda et al., OXO-TRICYANO COMPLEXES OF MOLYBDENUM(IV) AND TUNGSTEN(IV) WITH BIDENTATE SCHIFF-BASES, Transition metal chemistry, 20(3), 1995, pp. 291-294
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285
→ ACNP
Volume
20
Issue
3
Year of publication
1995
Pages
291 - 294
Database
ISI
SICI code
0340-4285(1995)20:3<291:OCOMAT>2.0.ZU;2-4
Abstract
The reaction of [M(CN)(4)O(OH2)](2-) (M = Mo or W) with 2-acetylpyridi
ne and methyl- or butyl-amine in a water-MeOH mixture gave [M(CN)(3)O(
L-L)](-) (L-L = Schiff base ligand), isolated as [AsPh(4)](+) salts. T
he complexes have been characterized by elemental analysis, and electr
onic, i.r. and H-1-n.m.r. spectroscopy. The Schiff base ligands comple
x in a bidentate manner through the two nitrogen atoms giving mixed-li
gand compounds similarly to 2,2'-bipyridyl or 1,10-phenanthroline.