GAS-PHASE PYROLYTIC REACTIONS - RATE DATA FOR THE PYROLYSIS OF PHENYL-N-TERT-BUTYLCARBAMATE AND THE HAMMETT CORRELATION FOR PYROLYSIS OF N-TERT-BUTYLBENZAMIDES

Authors
ALAWADI NA ALOMRAN FA MATHEW T
Citation
Na. Alawadi et al., GAS-PHASE PYROLYTIC REACTIONS - RATE DATA FOR THE PYROLYSIS OF PHENYL-N-TERT-BUTYLCARBAMATE AND THE HAMMETT CORRELATION FOR PYROLYSIS OF N-TERT-BUTYLBENZAMIDES, Journal of the University of Kuwait. Science, 22(1), 1995, pp. 53-59
Citations number
7
Categorie Soggetti
Multidisciplinary Sciences
Journal title
Journal of the University of Kuwait. Science → ACNP
ISSN journal
03764818
Volume
22
Issue
1
Year of publication
1995
Pages
53 - 59
Database
ISI
SICI code
0376-4818(1995)22:1<53:GPR-RD>2.0.ZU;2-M
Abstract
Rates of gas-phase thermal elimination of phenyl-N-tert-butylcarbamate have been measured between 593 and 648 K and compared to that of N-te rt-butylbenzamide and N-tert-butyl-acetamide. Also the gas-phase elimi nation reaction of substituted N-tert-butylbenzamides into alkene and substituted benzamides have been studied. The data give a good correla tion with sigma(O) value with rho + 0.43 at 720 K.