V. Fairen et B. Hernandezbermejo, MASS-ACTION LAW CONJUGATE REPRESENTATION FOR GENERAL CHEMICAL MECHANISMS, Journal of physical chemistry, 100(49), 1996, pp. 19023-19028
Power-law rates constitute a common approximation to the general analy
sis of the stability properties of complex reaction networks. We point
out in this paper that this form for the rates does not need to be as
sumed as an approximation for general rate laws; On the contrary, any
functional form for a rate law can be represented exactly in terms of
power laws. Moreover, we can uniquely associate to any set of kinetic
equations an equivalent ''conjugate'' representation in terms of the w
ell-known generalized Lotka-Volterra equations, standing for what we c
aliper capita rates, which amounts to a great simplification in terms
of the structural form of the mathematical representation of a reactio
n network.