Ba. Buffham et Iw. Cumming, PREVENTION OF PARTICLE DEPOSITION IN CROSS-FLOW MICROFILTRATION, Chemical engineering research & design, 73(A4), 1995, pp. 445-454
The likelihood of particles depositing on the filtering membrane in cr
ossflow microfiltration of dilute suspensions is investigated by calcu
lating steady-state particle concentration profiles. The profiles are
the result of the interaction of Brownian diffusion and hydrodynamic d
rag, electrostatic and van der Waals forces. It is shown that the ulti
mate equilibrium state is for particles to migrate to the filtering me
mbrane. However, the electrostatic force can be so strong that particl
es cannot reach the membrane in an observable period and a metastable
equilibrium then results. Factors that inhibit deposition are low ioni
c strength of the suspending liquid, high particle and membrane potent
ials, low Hamaker constant, low trans-membrane permeation rate and liq
uid viscosity, and large particle size.