In iron oxide powders positrons are trapped in the surface layers and
the value of the S-parameter is an indicator of the total specific sur
face, including external surface and internal surfaces of micropores.
The evolution of micropores is followed when alpha-FeOOH is thermally
decomposed into alpha-Fe2O3. It is shown that the micropore formation
is not linked to the decomposition process, but that they also form in
hematite synthesized from a ferrihydrite precursor in aqueous solutio
n.