NBNI2.38TE3, A NEW METAL-RICH NIOBIUM TELLURIDE WITH A STUFFED TAFE1+XTE3 STRUCTURE

Citation
J. Neuhausen et al., NBNI2.38TE3, A NEW METAL-RICH NIOBIUM TELLURIDE WITH A STUFFED TAFE1+XTE3 STRUCTURE, Inorganic chemistry, 34(14), 1995, pp. 3823-3825
Citations number
54
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00201669
Volume
34
Issue
14
Year of publication
1995
Pages
3823 - 3825
Database
ISI
SICI code
0020-1669(1995)34:14<3823:NANMNT>2.0.ZU;2-2
Abstract
The new metal-rich telluride NbNi2.38Te3 was synthesized and its struc ture determined by single-crystal X-ray methods. The structure consist s of NbNi2Te3-layers which are interconnected by Ni-atoms on partially occupied sites at the layer surfaces. NbNi2.38Te3 can be regarded as a stuffed variant of TaFe1+xTe3. Metal-metal interactions are importan t for the stability of this compound. NbNi2.38Te3 shows metallic condu ctivity.