CONVENIENT APPROACH TO THE DIRECT SYNTHESES OF CHROMIUM COMPLEXES FROM CHROMIUM(III) CHLORIDE

Efficient, new and direct synthetic routes for the syntheses of chromi um complexes of some N,N-donors, based on the reactions of a chromium( III) chloride salt and silver(I) complexes of the corresponding ligand s, have been described. It has been shown that syntheses of mixed-liga nd complexes of desired compositions may easily be achieved by followi ng these trans-metalation reaction routes. Comparison of the synthetic methodology with the reported methods has been noted.