SPECTROELECTROCHEMICAL CHARACTERIZATION OF SOLVENT-RELATED CHANGES INAXIAL LIGATION OF MANGANESE(II) AND MANGANESE(III) TETRAPHENYLPORPHYRINS

Authors
MUI XH SCHULTZ FA
Citation
Xh. Mui et Fa. Schultz, SPECTROELECTROCHEMICAL CHARACTERIZATION OF SOLVENT-RELATED CHANGES INAXIAL LIGATION OF MANGANESE(II) AND MANGANESE(III) TETRAPHENYLPORPHYRINS, Inorganic chemistry, 34(14), 1995, pp. 3835-3837
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
14
Year of publication
1995
Pages
3835 - 3837
Database
ISI
SICI code
0020-1669(1995)34:14<3835:SCOSCI>2.0.ZU;2-B
Abstract
Solvents with Gutmann donor numbers greater than or equal to 17 promot e dissociation of axial Cl- from Mn-III(TPP)Cl and Mn-II(TPPCl- produc ing six-coordinate Mn-III(TPP)(L)(2)(+) and five-coordinate Mn-II(TPP) (L). Systematic changes in the position of the Sorer band and the rela tive intensities of the Soret, Q(alpha), and Q(beta) bands provide a b asis for establishing the stoichiometries of these species.