DAVYDOV SPLITTING OF HERZBERG-TELLER-INDUCED VIBRONIC TRANSITIONS

Authors
PETELENZ P
Citation
P. Petelenz, DAVYDOV SPLITTING OF HERZBERG-TELLER-INDUCED VIBRONIC TRANSITIONS, Chemical physics letters, 240(5-6), 1995, pp. 605-609
Citations number
17
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
240
Issue
5-6
Year of publication
1995
Pages
605 - 609
Database
ISI
SICI code
0009-2614(1995)240:5-6<605:DSOHVT>2.0.ZU;2-S
Abstract
Based on a simple dimer model of vibronic coupling it is demonstrated that, contrary to the conventional notion, the Davydov splitting of th e fundamental vibronic transition in non-totally symmetric vibrations, induced by the Herzberg-Teller mechanism, does not need to be very sm all.