H. Ito et al., EFFECT OF PRESSURE AND SHEAR-STRESS ON CRYSTALLIZATION BEHAVIORS IN INJECTION-MOLDING, International polymer processing, 11(4), 1996, pp. 363-368
We studied in detail the effects of pressure and shear stress on the c
rystallization behaviors during injection molding process. Crystalliza
tion of isotactic-polypropylene (iPP) was simulated for various inject
ion flow rates. The crystallization started during the filling stage u
nder long filling condition. Moreover, the crystallization in some lay
ers showed two-step growth behavior, while in other layers the crystal
lization does not progress during the packing-cooling stage. Since pre
ssure becomes very high during molding process under long filling time
condition, the change of pressure is the most important factor govern
ing the crystallization.