X-ray diffraction, infrared, and Mossbauer spectroscopy techniques are
used to investigate Li0.5+0.5xGexFe2.5-1.5xO4; x less than or equal t
o 0.5. The polycrystalline samples show single-phase spinel structure.
The lattice constant for x greater than or equal to 0.2 is found to b
e nearly constant, but smaller than for x = 0. A small component of Fe
2+ has been detected in the IR spectra. The Mossbauer absorption patte
rns give magnetic sextets superimposed on a paramagnetic component tha
t increases with increasing germanium content. The average hyperfine h
eld at the A-site is found to decrease faster than at the B-site. A co
nsistent interpretation of the information obtained from the different
methods is provided. It is also suggested to give a qualitative expla
nation for the differential variation of the average hyperfine fields
at the two sites on the basis of supertransferred hyperfine interactio
ns.