Two types of gold can be distinguished in tetrahedrite from the Veitsc
h magnesite deposit, Austria. Primary gold present in unfractured mass
ive tetrahedrite, has a grain size up to 18 mum and contains, on avera
ge, Cu 8.73, Ag 7.01, Au 78.63 and Hg 2.35 (wt.%). Secondary gold is p
resent in fractures and is directly intergrown with digenite, covellit
e, Cu-thiosulphate, cuprite and chrysocolla but not with malachite or
azurite. The secondary gold is up to 200 mum in size with an average c
omposition of Cu 3.06, Ag 6.82, Au 86.41 and Hg 3.51 (wt.%). It is usu
ally closely intergrown with thiosulphates containing up to 0.21 wt.%
Au. This, together with the presence of 'dirty' gold with cloudy thios
ulphate inclusions, directly indicates the transport and deposition of
Au by a thiosulphate ligand. We believe this is the first reported di
rect evidence of gold transport and deposition by thiosulphate complex
es in a natural environment.