Chemical spray pyrolysis (CSP) offers a simple and inexpensive means o
f preparing metal-semiconductor composite (MSC) films with highly unus
ual optical properties. Oftentimes, these systems may involve metals i
n fairly complex semiconductors. Difficult at best to prepare, by stan
dard deposition techniques, they have been studied for possible applic
ations as nonlinear optical elements or photon detectors of optical ra
diation, among others. After discussing some general conditions for wh
ich the technique is applicable, results for the Ag-CuInSe2 MCS system
prepared by CSP are discussed in detail as an example.