STUDIES ON THE FORMATION OF 14-MEMBERED MACROCYCLES BY INTRAMOLECULARMICHAEL ADDITION

Authors
CREVISY C COUTURIER M DUGAVE C DORY YL DESLONGCHAMPS P
Citation
C. Crevisy et al., STUDIES ON THE FORMATION OF 14-MEMBERED MACROCYCLES BY INTRAMOLECULARMICHAEL ADDITION, Bulletin de la Societe chimique de France, 132(4), 1995, pp. 360-370
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
132
Issue
4
Year of publication
1995
Pages
360 - 370
Database
ISI
SICI code
0037-8968(1995)132:4<360:SOTFO1>2.0.ZU;2-0
Abstract
Intramolecular Michael addition of beta-ketoesters on enones 1, 2 and 3 with two conjugated unsaturations along the connecting chain led to cyclic monomers and dimers. These reactions work best with a cis alken e; they give poor yield of monomer with a trans alkene and no monomer with an alkyne.