DIELS-ALDER REACTIONS OF PHOSPHAALKENE AND PHOSPHADIENE COMPLEXES

Authors
TRAUNER H DELACUESTA E MARINETTI A MATHEY F
Citation
H. Trauner et al., DIELS-ALDER REACTIONS OF PHOSPHAALKENE AND PHOSPHADIENE COMPLEXES, Bulletin de la Societe chimique de France, 132(4), 1995, pp. 384-393
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
132
Issue
4
Year of publication
1995
Pages
384 - 393
Database
ISI
SICI code
0037-8968(1995)132:4<384:DROPAP>2.0.ZU;2-O
Abstract
Electron-rich dienes are well suited to cycloaddition reactions with u nstable phosphaalkene-Mo(CO)(5) complexes. The chemical properties of the resulting adducts have been examined briefly. (1-Phospha-1,3-diene )Mo(CO)(5) complexes are generated transiently from the corresponding 1,2-dihydrophosphetes and reacted with various dienophiles in Diels-Al der-like reactions. The above cycloadditions offer a general approach to dihydro- or tetrahydrophosphinines which are intermediates in the s ynthesis of new phosphinine derivatives.